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Her expression is so beautiful and moving- she looks so sad and unsure. I love the simplicity of the characters and the composition. The blur effect on the man in the background is really striking, too- it doesn't look muddy or smudged like I often see with depth of field blurs.
However my brain instantly recognized this as not being real or a photo once I clicked the thumbnail. I'm not sure if you want that slightly cartoony look or a more realistic one, but here are the things that made it obviously a 3D model:
-The colour of the eyes. They're too...vivid and un-natural. I've seen people with eyes like that but these ones here seem to have this blueish hue about them
-The skin is so soft and pure- while I can see some skin detail there needs to be more like slight wrinkles in her forehead, corner of mouth etc, even if she is young.
-I think the chin and nose look way too young- like that of a childs- yet the rest of her looks mature.
Regardless of these I do adore the style she's in, I wouldn't change it. I also really really love the lips. A lot.
Just my two cents.
Excellent work and grats on the DD my friend! <img src="e.deviantart.net/emoticons/l/l…" width="26" height="17" alt="" title="Love" />