007 - Dr. No.
Photoshop using Grut Brushes and Kyle's Real Oil Flat brushes.
The basic "how to" is here:
The process is very similar.
Grut Brushes: www.grutbrushes.com/
Kyle Brushes [Now at Adobe]: www.kylebrush.com/
I should add that this is a mock up and not an actual cover, Nor am I affiliated with Dynamite comics.